Hydrogenation with Organo-metallic Complex Catalysts.
نویسندگان
چکیده
منابع مشابه
Asymmetric Hydrogenation Catalysts
Iridium complexes with chiral N,P ligands have established themselves as efficient catalysts for the asymmetric hydrogenation of olefins, with largely complementary scope to Rh and Ru diphosphane complexes. In contrast to Rh and Ru catalysts, they do not require a coordinating polar group next to the C=C bond. Initial experiments with cationic phosphanyloxazoline (phox) complexes ([Ir(1)(cod)]X...
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O estudo de [Fe(CO)5], [Fe2(CO)9] e [Fe3(CO)12] como precursores catalíticos nas reações de hidrogenação do ciclohexeno e 1-hexeno foi efetuado. Um reator fotoquímico com fluxo de H2 e irradiação UV-vis foi usado no processo. Os espectros infravermelho das amostras mostraram a formação de [Fe(CO)4(olefina)] e [HFe(CO)3(π-alila)] como intermediários. A atividade mostrada do [Fe2(CO)9] na hidroge...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1964
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.22.975